Reactivit'Air

An important part of my Academy Research Fellow project (2017-2022) funded by Academy of Finland was the development of an instrument to measure total ozone (O3) reactivity. The paper describing the method we use, based on an idea by Dr. Detlev Helmig, and developed together with his group, has just been published in Atmospheric Measurement Techniques . At the time of my proposal submission in 2016, there had been only one publication on the topic of total O3 reactivity measurement by Prof. Jun Matsumoto (Waseda University, Tokyo, Japan). I was also aware of measurements that had been done by Dr. Helmig's group that had been presented at conferences. This is why I visited Prof. Matsumoto in Tokyo in December 2017 and then went to Boulder CO, U.S.A. , with Anssi Liikanen , in January 2018. Anssi stayed almost two months to work in Dr. Helmig's laboratory, performing many tests on the total O3 reactivity monitor (TORM).   Figure 1. Left: TORM at the Toolik Field Station, Alaska...

For many, 2020 will be remembered as quite a unique year, as many around the world are affected by the coronavirus pandemic and stay home for work, schools are closed, and everyone adapt to the unusual situation. In particular, for scientists, 2020 will be the year of the cancellations of not only international conferences, but also measurement campaigns. Last year, I was trying to organise a measurement campaign in Switzerland in 2020 for my projec t, but for various reasons, this was not possible. As an alternative, we decided to bring reactivity instruments (for both OH and ozone reactivity, the very first time this combination has been ever used to our knowledge) to Pallas in the Finnish Lapland in late March. As Anssi and I were preparing for the trip, COVID-19 slowly took on the news' cycle and Switzerland got hit quite badly by the pandemic. Did we just dodged a bullet? I guess we took a lucky decision without knowing. Still the first cases of COVID-19 were reported als...

It is a yearly routine: the temperature slowly increase and there is more light. It is then time to transport our instrumentation to the field! After our measurement campaign in Lapland last year (I wrote about it previously here and here ), this year we are back at the SMEAR II station in Hyytiälä in southern Finland. The SMEAR II station has become a hotspot for atmospheric sciences starting from the mid-1990s. The Finnish Meteorological Institute performs routine measurements there and research is also conducted at the site on Biogenic Volatile Organic Compounds (BVOCs) and other topics related to air quality. We performed an OH reactivity study at this site in 2016 (which is currently under review for Atmospheric Chemistry and Physics, see the open discussion ), which was building on previous studies by Sinha et al. (2010) and Nölscher et al. (2012) . Then, we extended the study period to include the spring and not only summer as the mentioned earlier studies. One result of ...

Just over a year in the REAC-FORTE project, we have a system running to measure ozone reactivity and we brought it a few weeks ago to the SMEAR II field station for proof-of-concept measurements. We are testing in real conditions the system that we developed based on our experience in Boulder with the group of Prof. Detlev Helmig. While in the lab the temperature and the relative humidity are quite stable, this is not the case in the forest. As the temperatures are decreasing and the relative humidity increase as autumn approaches, it is a good period to get preliminary measurements and to check that our system can run undisturbed when environmental conditions are changing. As none of our other on-line instrument to measure the air composition (gas chromatograph coupled to a mass spectrometer) is available at this time for simultaneous measurements, we collect air samples on adsorption tubes with the help of an auto-sampler (sampling time: 4 hours). These samples are then ana...

International collaboration is a cornerstone of modern science. This is why funding agencies generally make mobility an important part of any funding application. Academy of Finland is not different and my Academy Research Fellow project includes several instances of mobility. As I was preparing my proposal including ozone reactivity measurements, I was made aware of the unpublished work from Prof. Detlev Helmig and his team on this topic at the  Atmospheric Research Laboratory (ARL) , part of the  Institute for Arctic and Alpine Research (INSTAAR) at the University of Colorado in Boulder. After contacting Prof. Helmig, he agreed to host a laboratory visit in order for me to get familiar with their method. As the project got funded, the visit was settled for the beginning of 2018. Therefore, after visiting Prof. Matsumoto in Tokyo , I embarked on another trip, this time to the United States of America, and this time together with Anssi . I stayed for three weeks the...

Prof. Jun Matsumoto ( Waseda University , Tokyo, Japan) is one of the few researcher that has published about his experimental research on ozone reactivity. I recently visited his laboratory on the Tokorozawa Campus to discuss his research. As I was reading about ozone reactivity measurements for proposals, a name stood out: Prof. Jun Matsumoto. He published results from ozone reactivity measurements a few years ago (Matsumoto, 2014) and I contacted him to ask if he would be wiling to host me for a visit at the beginning of the project to familiarize myself with his method. He agreed and as the proposal got funded , I started to organize my trip to Tokyo, which took place at the end of November and beginning of December. Prof. Matsumoto met me on the first day at the Tokorozawa train station, next to my hotel, and we traveled together with train and bus to the university campus. There we first discussed about the current state of his research and on the following day, we visited ...

Today we are pleased to welcome M.Sc. Anssi Liikanen as a new member of the Air Quality group at the Finnish Meteorological Institute. Anssi starts his PhD studies during which he will develop ozone reactivity measurements and conduct field measurements. As a part of my  REAC-FORTE  project (Academy of Finland, grant 307797 ), ozone reactivity will be used as a tool to assess our understanding of tree emissions and air chemistry in forest air at high latitude (Finland) and high altitude (Switzerland). Biogenic volatile organic compounds emitted by vegetation, such as isoprene and monoterpenes, have a double carbon-carbon bond in their structures, enabling reaction with ozone. By comparing the total ozone reactivity with the reactivity expected from known emissions in combination with other measurement techniques, we will be able to know how much of the chemical composition of forest air is still not well understood. Anssi's background in atmospheric sciences with a focu...